Preheat the oven to 175°C or 350°F. Line two round 18cm cake tins.
Mix together all the dry ingredients (flour, sugar, baking powder, baking soda, cocoa powder, and salt) in a large bowl.
Mix the hot coffee (or boiling water), oil, vanilla extract, sour cream, and eggs in a medium bowl or jug, then pour it into the dry ingredients and mix until combined.
Pour the batter evenly into the two tins and bake for 30-35 minutes, or until a toothpick comes out clean or with a couple of crumbs stuck to it.
Allow the cakes to cool in the tins for 10 minutes before transferring them to a wire rack to cool completely.